Rubber Swell due to Gear oils

Where gear  oils  are  in  contact  with  rubber gaskets, seals, etc., the  action of  the  fluid on the  rubber compositions is of  importance. Consequently a Federal Test Method, 3604-T, has been set up. Such a test  can  be  varied as to  temperature, time and the  polymer     composition tested  depending upon  the    actual  service conditions of the  gear oil.

Thus, for ATF the following procedure is used. Sections of piston seals made from Acadia 3612 rubber compound are subjected to hot transmission fluid. Measurements of volume and hardness are made before and after the test. Two  seals are  cut  into  eight  sections each  and  the  sections  are  suspended  in  test  tubes  containing the lubricant and  held in a bath  at  300 degree F for  70  hours. The  sections are  then  cooled for  thirty  minutes  to  one hour in a  fresh  portion of the  test  fluid maintained at room  temperature. After wiping dry, the final volume and durometer readings are taken.

Polymers as components of gear lubricants

Polymers find application in gear lubricants both as additives and as actual fractions of the base fluids. Specific types of polymers used as additives will be mentioned later. Since the fluids in gear lubricants consist  primarily of mineral  oils  or of  asphaltic materials, any polymers  added  should  be compatible  with  the  major  ingredients. Likewise, polymerization  of  the added compounds  should  be complete  so that  no  further  thickening  occurs  in  service  even  if  the  mixture  is  subjected  to  some  heat. Most  polymeric  materials will  break  down  under  shearing  action  of gear  to  products  of  lower  molecular   weight  and  hence  any  initial  bodying  effect  may  be  partly  lost  after  use.

Although the polymers may be miscible with lubricating oils, special procedures may be necessary to introduce them into gear oils. Thus the grade of  polyisobutylene  which  is used  to  give  tackiness  or stringiness to oils is about  the  nature  of, but tougher than, crepe  rubber. Consequently this polymer is dispersed by a rubber mill in lubricating oil and the solution known as paratac is available to compounders. Also  most  grades of  polyethylene  are  of  such  a  nature that  only  prolonged  heat and  agitation  will  disperse them  in  lubricating oils.

The following polymers have been  suggested or  actually  used as components of  fluids for  gear lubricants: polyisobutylene  of various molecular  weight; styrene-polyisobutylene;  polyethylene ;and resins recovered  from  mineral oils. With the continued  investigation and  production of new  or  modified polymers it  seems  reasonable that  increasing  use  of  such  materials can  be expected in gear  lubricants.