Tuesday, November 13, 2012

Turbine Oils

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In many turbine installations the oil must  serve  not only the bearings  but  also  the  reduction  gearing and  perhaps the  thrust  elements. Therefore, consideration of this type of lubricant is necessary. The viscosity of the oil used in geared turbines is generally a compromise since the bearings would require a lower viscosity than the gearing. The base oil should be in the range of 300 to 500 SUS at 100 degree F. This oil should be  well refined  so that  it  will  have  long  life  and  so that  any naturally  occurring  compounds which might  contribute  to  emulsions are  removed. All of these points to solvent refined oils.
Alkyl  phenols, such as 2, 6-ditertbutyl – 4 – methyl phenol, or “Ionol” in a  proportion of 0.1 to 1 per cent are  satisfactory  oxidation  inhibitors for  most  turbine  oil formulations.
Rust  inhibitors should  be  of a nature  which  will not  contribute  to  emulsions nor  be  removed  from the oil by water. Or this reason “Lubrizol 850” or “Alox 1832” can be used. The former is effective in concentrations o 0.05 to 0.10 per cent and the latter in amount up to 2.5 per cent.

An  antifoaming  agent,  such  as a dimethyl  silicon polymer, in  a  concentration of about 0.001  per cent, should  be  present  in turbine  oils.

According to Landis et al. the emulsive tendencies of antirust turbine oils can be reduced by the addition of small amounts of aryl sulfonic acids or their salts. A typical composition  consists of : a solvent  refined  oil having  a viscosity  of 350 to 600 SUS  at  100 degree F  and  containing  0.25  per cent  by  weight  of  2, 6 – ditertbutyl -4 – methylphenol; 0.1 per cent  of  phenyl  alpha  naphthylamine; 0.1 per cent  of an  antitrust  agent obtained   by  reacting  oleic  acid  with  triethylenetetramine, in a molar ratio of 1.3  to 1, to  produce an  intermediate  product  which  is  then  reacted  with  triisobutenyl  succinic  acid  anhydride in a molar  ratio of 2.3 to 1; and  0.02 per cent  of sodium  petroleum  sulfonate. As  a  substitute  for  the  last  ingredient, 0.02 per cent  of either barium  or zinc  petroleum  sulfonate  or  0.05 per cent  of  ammonium  petroleum sulfonate, can  be used. The proportion of such demulsifies is critical and an excess defeats the purpose.





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