Demulsibility of gear oils

Lubricating oils vary in their tendency to emulsify with water; therefore, if emulsification of gear oils is likely to be a problem, the base oil should be investigated. Any polar compounds remaining in the oil after refining, such as sulfonates, petroleum acids, and even asphaltic bodies, may help to stabilize emulsions. Well refined oils of low viscosity  will  have  the  least  tendency  to  from  permanent  emulsions  with  water.

High interfacial tension will tend to cause emulsions to break. Many oil field emulsions are broken by causing the emulsion to revert from water in oil type to oil in water type. However, the best solution for this type of trouble is to choose oil additive combinations which do not promote emulsification.

Corrosion prevention by gear lubricants

Ellis et al.^22 consider that staining, tarnishing, and rusting are all  indications of corrosion. The thought is that light stain or tarnish represents the early stages of corrosion since, unfortunately these  changes do not proceed very far before pitting starts. Unreactive gear oils, which have not been subjected to excessive high temperature oxidation, have no tendency  to corrode  metals but, under moist or humid conditions or in the presence of  most salts or acids, do not offer proper protection against  rusting of ferrous  metal  surfaces such as gears. However, additives can be included in gear compounds which will provide rust prevention. Where conditions of incipient rusting prevail, the gears and other metal parts even to the inside of the gear case may require protection, particularly when idle. In such cases not only will the presence of a rust inhibitor but also the viscosity of the base oil be factors. Thus, the higher the viscosity of the gear lubricant, the slower this will drain from the metal surfaces and consequently the greater the rust prevention. Rusting may occur in different environments and various theories are offered as to the mechanisms of corrosion, but normally moisture and oxygen are the offenders

Most rust preventives are polar substances, such as long chain fatty acids, fatty amines, metal sulfonates, certain esters, oxidized petroleum fractions, etc. Such materials wet a metal surface preferentially and displace any water which may come in contact with the steel. The coating of polar substance then acts as a barrier against water reaching the metal surface.

As previously mentioned, controlled  corrosion due  to  EP  additives  is generally beneficial in  that  it  corrodes  away high  spots   on the gear  teeth after  which corrosion may decrease. With the proper selection of the chemical agents, these are not activated except under extreme conditions of load and /or temperature. Further, most of the EP additives which are  used  in  gear  lubricants will have little effect  upon  other  metals such  as bronze, copper, etc; at the bulk oil temperatures maintained  in normal  gear operation .