Wednesday, May 30, 2012

Freedom from separation in gear oils

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Precipitation or settling of some components in gear oils is sometimes noted. This most often occurs in mixtures containing EP additives. The separation may be due to lack of solubility or to reaction of ingredients resulting in formation of sludge. Since such additives are often present in concentrations of 9 per cent or more, the base oil must keep a high proportion of heavy chemical compounds in dispersion or suspension. Both additive manufacturers and oil blenders select ingredients which will keep any separation of such agents at a minimum.  
Fletcher^23 selected three SAE 90 hypoid gear lubricants and three multipurpose SAE 90 oils meeting MIL-L-002105A specification. By precipitation tests, the first three oils showed some sludge in the unused oil which increased after a service test in two of the lubricants. In the multi-purpose oils there was only a trace of sludge before use but measurable amounts up to 7 per cent after the tests.
Of course, settling or sludge formation in gear lubricants results in loss from the action zone of valuable active ingredients, but the greatest concern is the effect sludge may have on operating mechanisms. Thus, Fletcher^23 mentions that precipitation of sludge out of oil due to centrifuging in transmission cases may result in carbon like deposits in pocket bearing positions, internal clutch teeth, and in some cases in oil grooves  and synchronizer grooves. It is conceivable that such deposits could adversely affect the operation of the unit. This fact was probably recognized by one tractor manufacturer who specified that oils used in their equipment should be filterable, thus, indicating that sludge should not separate during  normal operation.
Where sludge is formed in EP gear oils the action is accelerated by increasing temperature. It is therefore probably a result of reaction of the chemical compounds which constitute the EP additives. Detergent agents do not seem to be a correction for such sludge separation, and any improvement in the condition probably lies in selection of the EP additives.

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