Calcium in Lubricating Oil

While the ASTM Methods and Fed. Test Method use the same sample  for  determination  of  several  metals, the IP  Methods  is  specifically concerned with  calcium  analysis. This calls  for ashing  followed  by determination  of the  calcium  either  as oxide  or oxalate.

Chemical Analysis for Metals in Lubricating oils

These methods of chemical analysis are intended  for the  determination of barium, tin, silica, zinc, aluminum, calcium, magnesium, sodium and potassium in  new  and used  lubricating  oils. Other metallic elements, sulfur, phosphorus and  chlorine in  amounts  commonly  found  in lubricating  oils  do not  interfere in this  method.

Essentially,  the  method  consists  of  igniting  the sample, dissolving  the  residue  in  mineral acid and  then  separating  the various  metals by  conventional  methods.  

Radioactive Tests for Metals in Oils

Tests in which the radioactivity of metals or their compounds is used as a means of determining their presence or concentration are largely confined to experimental investigations. This  is true  because, first  activated metals or  compounds must  be present  and  this is not true of  commercial  lubricants and second, the life  of some of the  isotopes  used  is short so that  after  prolonged service the activity would  almost  disappear.

The Navy Gear Wear Tester

The Navy Gear Wear Tester is described in Federal Methods 791, Methods 335. The  equipment  makes  use  of  small  brass and  steel  gears,  but  Ninos  has  also  used  mating  gears  of other metals, such  as  brass on  stainless  steel, Phosphor  Bronze, and  ST Aluminum   on  SAE     4130 steel  and  SAE B-1112  steel  against  stainless  steel.

In  the  test  two  helical  gears  of  dissimilar  metals, each  approximately  one half inch  in  diameter are  rotated  together  as the  driving  motor  delivers a simple  harmonic motion     of 4.0  inches  amplitude  and  40 cycles per minute, through a  crack  to  the  upper  brass gear. This gear  oscillates  approximately  one  revolution while  a torque load of about  three  and  one  half inch pounds  is applied to  the  test  gears by  means  of a seven  pound  weight. The  gears  are  oscillated  for the  desired  number  of  cycles, or until gear  tooth  failure  due  to  excessive  wear  occurs. At the completion of the test, the gears are removed from the fixture, cleaned as before, and reweighed to    determine weight loss. The wear rate in mg for 10,000 cycles is then calculated permitting a comparison of different lubricants. New  test  gears  are  used  for  each  run even  though  there  is  virtually  no wear  of the  steel  gear  as  compared  to the  brass  gear.

Both fluid products and lubricating greases can be tested as gear lubricants on this apparatus. Indications  are  that  with  increase  in viscosity  of  gear  oils  the  gear wear   decreases. No  speculations are  given  as to how  much  of    the  wear  might  be  due  to abrasion which  is due  to particles  from  the gears.

Minimum action of gear oils on components of mechanisms

Well refined mineral lubricating oils have little if any action on most metals, particularly ferrous metals. It is only upon prolonged use at elevated temperatures that such oils may from compounds which will act upon metals. Since such oil changes can be retarded or almost completely arrested by the use of oxidation inhibitors and also metal deactivators or pacifiers can be included, there should be little concern about the action of straight mineral oils upon the metal components with which they come in contact.

What we are concerned with here is the action on parts made from other materials, such as paper, plastics, rubber, etc. Seals are likely to be made from rubber, either artificial or natural, and any deterioration of the compositions due to the lubricant should be at a minimum. Many seals consist of compounded materials, such as “neoprene,” and it is found that oils high in aniline points, as are most high V.I. oils, will have little effect on this compound.

Automatic transmission mechanisms may be found to contain paper and “Nylon” parts. In future devices which will require transmission fluids, a greater variety of components may be used. The safest course when supplying oils for contact with unusual materials is to have the fluids pretested to determine their suitability.