Nuclear Power plants Gear Lubrication

Present indications are that the principal gearing in nuclear power plants will be in connection with turbines. Such  reduction units should be  far  enough removed  from the area of high  radiation that no degradation  of the oil  from such  a source  will occur.

Cox et al.^14 who have considered this matter state: “Irradiation tests of turbine oils show that maximum expected radiation doses in  current and projected power plants over a twenty year period  does not change the  physical  properties of the oil. Oxidation stability and other properties are, therefore, still of most importance in turbine oil selection”.

Also  Okrent^43  in treating  design considerations of nuclear powered  surface vessels concludes that the  reduction gearing  in connection with  the  turbine presents no problems  from a radiation standpoint. In spite of the  above thoughts, Watson^51  mentions  that in  nuclear  power  generating  stations, a  number of applications  will be found where  gears  should  be run  without  lubrication. Experiments were, therefore, made with various materials, run in a dry state, with latter wear. As a  result, it is suggested that if loads are not heavy, spur gears, made of  case hardened  En steel, phosphate prior to coating  the flanks with  molybdenum  disulfide, can  be run  continuously, in a dry state, without  measurable  wear. Also  a worm wheel , made  from  woven  asbestos base  with  a case  hardened  steel worm, is promising for  operation in a dry  state.

No doubt, when and if gear oils with radiation resistance are necessary, suitable fluids will have been developed. Thus, polybenzenoid   compounds containing short alkyd groups show promise in such applications.

One  interested  in this subject might  avail himself  of a series of  eight  papers devoted to “Non-conventional  Lubricants  and Bearing  Materials such  as Are Used  in Nuclear  Engineering”. These were presented at the Manchester college of Science and Technology on April 12, 1962 by the lubrication and Wear Group of The Institute of Mechanical Engineers (British).   

Oxidation stability of gear lubricants

Once a proper gear lubricant is selected for a given application it should suffer a minimum chemical and physical change during use. One of the changes most likely to occur is oxidation  of  the oil  which ultimately  will  lead  to the formation of undesirable  products  and  changes in the characteristics  of the oil. Such changes may result in the formation of acidic  products which  may corrode  the metal  surfaces, in an increase  in viscosity  of  the  oil, or in production  of  insoluble  materials. Oxidation  of  lubricants  is  accelerated  by  high  temperatures or  by  the  presence of  certain catalysts, particularly  soluble  metals. The  immediate  effects  of  oxidation  may appear  beneficial  in  that  petroleum  acids formed  function  as  oiliness  agents, perhaps by  the formation  of  monolayers  of metallic  soaps. Ultimately, as oxidation of oil proceeds, the harmful effects become evident. The degradation of the oil by oxidation may result in not only the formation of acidic products but also asphaltenes, resins, or other polymers. Changes in the lubricant will  probably  be  accompanied  by  increase  in  viscosity , darkening  in  color, and  the  formation  of  sludge. Cases have been noted where gear oils became almost solid due to oxidation.

However, oxidation of gear lubricants can be retarded by addition of antioxidants or oxidation inhibitors. The use of such agents in most gear oils is wise since the environment for the lubricants is favorable for oxidation in that both air and heat are present and thin films of the oil are in contact with the air.

The mechanism of the action of antioxidants is generally considered to be that of chain breaking as the additive reacts with a “hot” molecule, thus being itself oxidized. In this process the oxidant molecule is destroyed, but with dissipation of the energy possessed by the “hot” molecule, so that the chain reaction is broken. Thus, the oxidation of hundreds or perhaps thousands of molecules of hydrocarbons is prevented, since the energy would be passed on from one molecule to the next in the normal chain reaction.

The suggestion was made by Larsen and Diamond^35 that antioxidants may be either inhibitors or retardants, the former acting to break reaction chains and the latter being converted into an inhibitor during the oxidation process. Three possibilities were given by Murphy et al.^42  for the possible disposition of such inhibitors after they had reacted: (a) the inhibitor is oxidized to a compound which is incapable of further antioxidant action; (b) the inhibitor is oxidized to a compound which still exhibits antioxidant action, but generally to a reduced extent; (c)  the inhibitor is capable of regeneration. The latter type of additive is the most desirable, provided the rate and degree of regeneration are high.

Specific compounds suitable as antioxidants will be suggested in a later section, but most of these agents fall in the following bellows: (a) various types of phenols, (b) certain sulfur bearing compounds, (c) numerous organic phosphites, and (d) certain of the amines. A number of additives function as dual purpose agents and thus, in some cases, a specific antioxidant may not be required.

Corrosive wear

Corrosive   wear  in  the  presence of a gear  lubricant may  be  due to the  environment if air, water , or electrolytes  are  present. If gear cases are not tight and high humidity prevails, rusting may occur, not only on idle gears above the oil line, but also on the walls of the gear case. If necessary, rust preventive compounds can be added to gear oils to counteract the action of moisture. Such additives may be polar compounds, often containing long chains, which will be adsorbed at the metal oil interface to form hydrophobic films. Prevention of corrosion due to electrolytes may be more difficult than prevention of rusting. However, if the contaminant is salt, the same types of additives as mentioned above will aid in corrosion prevention. If water soluble acids entering the gear case cannot be prevented, ordinary gear oils will not serve to prevent corrosion. In this case it may be necessary to use gears of different composition. Stainless steel will resist most acids and some electrolytes. High silica irons, while somewhat brittle, also have this faculty.

The corrosive wear most apt to occur in gear operations is that due to chemical additives, known as EP agents. The secret of a satisfactory EP gear oil is to obtain controlled  corrosion so that welding  of  the  metal  surfaces  will not take place  and  yet  asperities will  be  reduced. In  the  case of most EP gear oil  compositions  corrosive  wear  should  not  be excessive and  is actually  beneficial in  that it extends the life of the gears under extreme operating  conditions