Adhesion of gear and transmission lubricants

Adhesion is a comparative term, and what is in mind in this case is stickiness which will insure that the lubricant will resist the action of centrifugal force and thus remain on the gear teeth. This quality is most important in the case of open gears. Desirable adhesion is obtained by the use of high molecular weight and high softening point compounds. That is, asphaltic residua, resins, and polymers are largely used for the purpose. Which this type of product is desirable for open gears, it is not suitable for most gear sets because of its high fluid friction and poor cooling effect.

Corrosive wear

Corrosive   wear  in  the  presence of a gear  lubricant may  be  due to the  environment if air, water , or electrolytes  are  present. If gear cases are not tight and high humidity prevails, rusting may occur, not only on idle gears above the oil line, but also on the walls of the gear case. If necessary, rust preventive compounds can be added to gear oils to counteract the action of moisture. Such additives may be polar compounds, often containing long chains, which will be adsorbed at the metal oil interface to form hydrophobic films. Prevention of corrosion due to electrolytes may be more difficult than prevention of rusting. However, if the contaminant is salt, the same types of additives as mentioned above will aid in corrosion prevention. If water soluble acids entering the gear case cannot be prevented, ordinary gear oils will not serve to prevent corrosion. In this case it may be necessary to use gears of different composition. Stainless steel will resist most acids and some electrolytes. High silica irons, while somewhat brittle, also have this faculty.

The corrosive wear most apt to occur in gear operations is that due to chemical additives, known as EP agents. The secret of a satisfactory EP gear oil is to obtain controlled  corrosion so that welding  of  the  metal  surfaces  will not take place  and  yet  asperities will  be  reduced. In  the  case of most EP gear oil  compositions  corrosive  wear  should  not  be excessive and  is actually  beneficial in  that it extends the life of the gears under extreme operating  conditions